题 目：Stabilization of Highly Reactive Group 13 and 15 Species
报告人：Dr. David A. Ruiz
Ph.D in Inorganic Chemistry
Advisor: Prof. Dr. Guy Bertran (Associate editor of Chemical Reviews)
Department of Chemistry & Biochemistry
University of California, San Diego
时 间：2016年4月22日（周五）上午10:30
地 点：卢嘉锡楼202报告厅
报告摘要：
Developed nucleophiles based on trivalent boron centers, which are typically Lewis acids, and applied them as stronger donor ligands compared to ubiquitous group 15 ligands. Designed a rational synthesis to generate carbene-antimony species in the formal oxidation states of three, two, one, and zero, illustrating a rare example of a single ligand stabilizing an element in four different oxidation states. Recently, exploring compounds that feature monovalent phosphorus centers and their reactivity, especially towards metals.
